La Roche-Posay Anthelios UVMune 400 Oil Control Gel-Cream SPF 50+ Fragrance Free Versus La Roche-Posay Toleriane Double Repair Matte Face Moisturizer for Oily Skin
This chemical sunscreen covers the full UV range and blocks ~98% of UVB at SPF 50.
This oil-control moisturizer is formulated around Silica and Niacinamide to balance excess oil and strengthen the skin barrier.
What's inside
What's inside
Key Ingredients
Benefits
Concerns
Ingredients Side-by-side
Water
Skin ConditioningDiisopropyl Sebacate
EmollientSilica
AbrasiveAlcohol Denat.
AntimicrobialEthylhexyl Salicylate
UV AbsorberEthylhexyl Triazone
UV AbsorberBis-Ethylhexyloxyphenol Methoxyphenyl Triazine
Skin ConditioningDiisopropyl Adipate
EmollientPEG-8
HumectantDipropylene Glycol
HumectantC12-22 Alkyl Acrylate/Hydroxyethylacrylate Copolymer
StabilisingGlycerin
HumectantDrometrizole Trisiloxane
UV AbsorberAluminum Starch Octenylsuccinate
AbsorbentButyl Methoxydibenzoylmethane
UV AbsorberMethoxypropylamino Cyclohexenylidene Ethoxyethylcyanoacetate
StabilisingTocopherol
AntioxidantDiethylamino Hydroxybenzoyl Hexyl Benzoate
UV FilterAcrylates Copolymer
Acrylates/C10-30 Alkyl Acrylate Crosspolymer
Emulsion StabilisingBixa Orellana Seed Extract
MaskingCaprylyl Glycol
EmollientCitric Acid
BufferingHydroxyacetophenone
AntioxidantMaltodextrin
AbsorbentPentaerythrityl Tetra-Di-T-Butyl Hydroxyhydrocinnamate
AntioxidantPentylene Glycol
Skin ConditioningSilica Silylate
EmollientSodium Polyacrylate
AbsorbentTerephthalylidene Dicamphor Sulfonic Acid
UV AbsorberTriethanolamine
BufferingTrisodium Ethylenediamine Disuccinate
Zinc PCA
HumectantWater, Diisopropyl Sebacate, Silica, Alcohol Denat., Ethylhexyl Salicylate, Ethylhexyl Triazone, Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine, Diisopropyl Adipate, PEG-8, Dipropylene Glycol, C12-22 Alkyl Acrylate/Hydroxyethylacrylate Copolymer, Glycerin, Drometrizole Trisiloxane, Aluminum Starch Octenylsuccinate, Butyl Methoxydibenzoylmethane, Methoxypropylamino Cyclohexenylidene Ethoxyethylcyanoacetate, Tocopherol, Diethylamino Hydroxybenzoyl Hexyl Benzoate, Acrylates Copolymer, Acrylates/C10-30 Alkyl Acrylate Crosspolymer, Bixa Orellana Seed Extract, Caprylyl Glycol, Citric Acid, Hydroxyacetophenone, Maltodextrin, Pentaerythrityl Tetra-Di-T-Butyl Hydroxyhydrocinnamate, Pentylene Glycol, Silica Silylate, Sodium Polyacrylate, Terephthalylidene Dicamphor Sulfonic Acid, Triethanolamine, Trisodium Ethylenediamine Disuccinate, Zinc PCA
Water
Skin ConditioningGlycerin
HumectantSilica
AbrasiveBetaine
HumectantNiacinamide
SmoothingCetearyl Isononanoate
EmollientZea Mays Starch
AbsorbentCeramide NP
Skin ConditioningCarbomer
Emulsion StabilisingGlyceryl Stearate Citrate
EmollientSodium Hyaluronate
HumectantSodium Hydroxide
BufferingPerlite
AbsorbentHydroxyacetophenone
AntioxidantCaprylyl Glycol
EmollientXanthan Gum
Emulsifying
Reviews
Ingredients Explained
These ingredients are found in both products.
Ingredients higher up in an ingredient list are typically present in a larger amount.
Caprylyl Glycol is a humectant, skin conditioner, emollient, and preservative booster derived from either caprylic acid or synthetically created.
Typical use levels vary from 0.3-1% as a preservative booster and go up to 2% to condition skin.
Because it is not a free-fatty acid, this ingredient is fungal acne safe (there's nothing for Malassezia to feed on).
Learn more about Caprylyl GlycolGlycerin (or glycerol) is a compound naturally found in your skin. It's a powerhouse humectant that pulls water into the stratum corneum.
Topically, glycerin does several things at once:
Your skin makes glycerin on its own (mostly from sebaceous oil breakdown) and shuttles it to your outermost layer of skin, or your epidermis, via aquaporin-3.
Aquaporin-3 is a transporter that is essential for normal skin hydration, elasticity, and repair. Interestingly, mice lacking in AQP3 have dry and less elastic skin that can be fully corrected with glycerin.
This ingredient is non-irritating, plays well with almost every ingredient, and works across all skin types. Typical use is anywhere between 3-10% but can go up to 79% in some leave-on products.
Just know very high concentrations (>40%) can feel tacky in low humidity.
Glycerin is the name for this ingredient in American English. British English uses Glycerol/Glycerine.
Learn more about GlycerinHydroxyacetophenone is a small phenolic molecule that earns its place in a formulas as an antioxidant and preservative booster.
As a phenol, it is able to neutralize free radicals to protect both the product and the skin from oxidative stress.
Though it can't kill microbes on its own, it works as a good supporting agent when combined with other preservatives like Phenoxyethanol or 1,2-Hexanediol.
This ingredient naturally occurs as piceol in Norwegian spruce needles (~0.4-1.1% dry weight and in cloudberries). Though the cosmetic-grade material is synthesized for purity and consistency.
You'll usually see it used at low levels and suppliers recommend up to 1% added to a water phase.
Safety testing was done at concentrations like 0.05% in SPF products and 0.5% in a Human Repeated Insult Patch Test. The safety evidence is assuring; this ingredient is safe for cosmetics in current use and also holds safety status as a food flavoring as well.
An honest caveat: the "soothing" and "anti-inflammatory" claims come mostly from supplier marketing rather than published clinical trials. The Cosmetic Ingredient Review's own literature search found no useful efficacy studies on this ingredient.
So the antioxidant and preservative-boosting roles are the well supported ones while the calming benefit is plausible but thinly evidenced.
Overall, this is a well-tolerated, low-irritation multitasker that quietly helps a formula stay fresh and stable.
Learn more about HydroxyacetophenoneSilica, also known as silicon dioxide, is a naturally occurring mineral. It is used as a fine, spherical, and porous powder in cosmetics.
Though it has exfoliant properties, the function of silica varies depending on the product.
The unique structure of silica enhances the spreadability and adds smoothness, making it a great texture enhancer.
It is also used as an active carrier, emulsifier, and mattifier due to its ability to absorb excess oil.
In some products, tiny microneedles called spicules are made from silica or hydrolyzed sponge. When you rub them in, they lightly polish away dead skin layers and enhance the penetration of active ingredients.
Learn more about SilicaWater. It's the most common cosmetic ingredient of all. You'll usually see it at the top of ingredient lists, meaning that it makes up the largest part of the product.
So why is it so popular? Water most often acts as a solvent - this means that it helps dissolve other ingredients into the formulation.
You'll also recognize water as that liquid we all need to stay alive. If you see this, drink a glass of water. Remember to stay hydrated!
Learn more about Water