Unsun Cosmetics Mineral Tinted Face Sunscreen Lotion - SPF 30 Versus Shiseido Urban Environment Oil-Free UV Protector Broad Spectrum Face Sunscreen SPF 42
This mineral sunscreen covers the full UV range and blocks ~97% of UVB at SPF 30.
This mineral sunscreen covers the full UV range and blocks ~98% of UVB at SPF 42.
What's inside
What's inside
Key Ingredients
Benefits
Concerns
Ingredients Side-by-side
Titanium Dioxide 3%
Cosmetic ColorantZinc Oxide
Cosmetic ColorantAllantoin
Skin ConditioningAlumina
AbrasiveButyrospermum Parkii Butter
Skin ConditioningCamellia Oleifera Leaf Extract
AstringentCetyl PEG/PPG-10/1 Dimethicone
EmulsifyingCucumis Sativus Extract
Skin ConditioningCyclopentasiloxane
EmollientDimethicone Crosspolymer
Emulsion StabilisingDisteardimonium Hectorite
StabilisingEthylhexylglycerin
Skin ConditioningGlycerin
HumectantHexyl Laurate
EmollientIron Oxides
Lavandula Angustifolia Oil
MaskingLinum Usitatissimum Seed Oil
PerfumingOenothera Biennis Oil
EmollientPEG-10 Dimethicone
Skin ConditioningPhenoxyethanol
PreservativePlankton Extract
Skin ConditioningPolyglyceryl-4 Isostearate
EmulsifyingPolymethylsilsesquioxane
Rosa Canina Seed Oil
EmollientSilica
AbrasiveStearic Acid
CleansingTocopheryl Acetate
AntioxidantTriethoxycaprylylsilane
Water
Skin ConditioningTitanium Dioxide 3%, Zinc Oxide, Allantoin, Alumina, Butyrospermum Parkii Butter, Camellia Oleifera Leaf Extract, Cetyl PEG/PPG-10/1 Dimethicone, Cucumis Sativus Extract, Cyclopentasiloxane, Dimethicone Crosspolymer, Disteardimonium Hectorite, Ethylhexylglycerin, Glycerin, Hexyl Laurate, Iron Oxides, Lavandula Angustifolia Oil, Linum Usitatissimum Seed Oil, Oenothera Biennis Oil, PEG-10 Dimethicone, Phenoxyethanol, Plankton Extract, Polyglyceryl-4 Isostearate, Polymethylsilsesquioxane, Rosa Canina Seed Oil, Silica, Stearic Acid, Tocopheryl Acetate, Triethoxycaprylylsilane, Water
Water
Skin ConditioningDimethicone
EmollientIsododecane
EmollientSd Alcohol 40-B
AstringentDipropylene Glycol
HumectantEthylhexyl Palmitate
EmollientPEG-10 Dimethicone
Skin ConditioningGlycerin
HumectantPolymethylsilsesquioxane
Vinyl Dimethicone/Methicone Silsesquioxane Crosspolymer
Polybutylene Glycol/PPG-9/1 Copolymer
Skin ConditioningDimethicone/Vinyl Dimethicone Crosspolymer
Skin ConditioningXylitol
HumectantMethyl Methacrylate Crosspolymer
Thiotaurine
AntioxidantScutellaria Baicalensis Root Extract
AstringentPaeonia Albiflora Root Extract
Skin ConditioningOnonis Spinosa Root Extract
AntiseborrhoeicEctoin
Skin ConditioningLauryl PEG-9 Polydimethylsiloxyethyl Dimethicone
Skin ConditioningHydrogen Dimethicone
Butylene Glycol
HumectantDisodium EDTA
Disteardimonium Hectorite
StabilisingAlumina
AbrasiveBHT
AntioxidantTriethoxycaprylylsilane
Syzygium Jambos Leaf Extract
Skin ConditioningTocopherol
AntioxidantPhenoxyethanol
PreservativeBenzoic Acid
MaskingParfum
MaskingTitanium Dioxide
Cosmetic ColorantMica
Cosmetic ColorantWater, Dimethicone, Isododecane, Sd Alcohol 40-B, Dipropylene Glycol, Ethylhexyl Palmitate, PEG-10 Dimethicone, Glycerin, Polymethylsilsesquioxane, Vinyl Dimethicone/Methicone Silsesquioxane Crosspolymer, Polybutylene Glycol/PPG-9/1 Copolymer, Dimethicone/Vinyl Dimethicone Crosspolymer, Xylitol, Methyl Methacrylate Crosspolymer, Thiotaurine, Scutellaria Baicalensis Root Extract, Paeonia Albiflora Root Extract, Ononis Spinosa Root Extract, Ectoin, Lauryl PEG-9 Polydimethylsiloxyethyl Dimethicone, Hydrogen Dimethicone, Butylene Glycol, Disodium EDTA, Disteardimonium Hectorite, Alumina, BHT, Triethoxycaprylylsilane, Syzygium Jambos Leaf Extract, Tocopherol, Phenoxyethanol, Benzoic Acid, Parfum, Titanium Dioxide, Mica
Reviews
Ingredients Explained
These ingredients are found in both products.
Ingredients higher up in an ingredient list are typically present in a larger amount.
Alumina (aka aluminum oxide) is an inorganic mineral powder refined from bauxite that works as a quiet workhorse in a formula.
It shows up often as an abrasive, absorbent, anticaking, bulking, and viscosity-controlling agent.
One of its most common jobs is acting as a pigment carrier and dispersant.
Alumina platelets are often blended with inorganic sunscreens like Titanium Dioxide (or with colorants) and then coated with a silicone such as Triethoxycaprylylsilane so the pigment spreads evenly and smoothly.
In makeup, it can also double as a light-diffusing powder or oil absorber to keep formulas from looking greasy.
The Cosmetic Ingredient Review Expert Panel has concluded alumina to be safe in present practices of use and concentration.
They note it's a stable, oxidized compound and scientific research has failed to establish links to health issues.
Concentrations vary depending on the product:
Learn more about AluminaDisteardimonium Hectorite comes from the clay mineral named hectorite. It is used to add thickness to a product.
It can also help stabilize a product by helping to disperse other ingredients.
Hectorite is a rare, white clay mineral.
Learn more about Disteardimonium HectoriteGlycerin (or glycerol) is a compound naturally found in your skin. It's a powerhouse humectant that pulls water into the stratum corneum.
Topically, glycerin does several things at once:
Your skin makes glycerin on its own (mostly from sebaceous oil breakdown) and shuttles it to your outermost layer of skin, or your epidermis, via aquaporin-3.
Aquaporin-3 is a transporter that is essential for normal skin hydration, elasticity, and repair. Interestingly, mice lacking in AQP3 have dry and less elastic skin that can be fully corrected with glycerin.
This ingredient is non-irritating, plays well with almost every ingredient, and works across all skin types. Typical use is anywhere between 3-10% but can go up to 79% in some leave-on products.
Just know very high concentrations (>40%) can feel tacky in low humidity.
Glycerin is the name for this ingredient in American English. British English uses Glycerol/Glycerine.
Learn more about GlycerinPeg-10 Dimethicone is silicone with conditioner and emulsifier properties. It mostly acts as an emollient in skincare and and humectant in haircare.
According to the manufacturer, acidic formulations decrease the stability of this ingredient. It works best in neutral or near neutral formulations.
Phenoxyethanol is one of the most widely used preservatives in skincare (and for good reason!).
It has a large spectrum of antimicrobial activity and especially effective bacteria, yeast, and mold while only having a weak effect on your skin's natural microbiome.
On a cellular level, it disrupts the cell membranes of microbes by poking holes that make the cell leak. This shuts down the chemical reactions the microbe needs to make energy so it can no longer survive.
Another perk of this ingredient is that it stays functional across a wide pH range (3-10).
You'll often see it paired with boosters like Ethylhexylglycerin; one study showed that a 1:9 ratio of Ethylhexylglycerin to Phenoxyethanol damages bacterial membranes as effectively as doubling the Phenoxyethanol concentration on its own.
Typical use concentrations range from 0.3-1% depending on the formula, and this ingredient is capped at 1% int the EU.
Safety-wise, the fear mongering does not hold up to the evidence. The EU's Scientific Committee on Consumer Safety and FDA consider it safe as a preservative at up to 1%, including for children of all ages.
Adverse systemic effects only showed up in animal studies at exposures roughly 200x higher than what people get from cosmetics. And despite its very widespread use, this ingredient is a rare sensitizer and allergic reactions are uncommon.
Learn more about PhenoxyethanolPolymethylsilsesquioxane is a silicone used as a film forming agent.
When applied to the skin, this ingredient creates an invisible film on the surface. This film still allows oxygen to pass through, but prevents moisture from escaping. This can help condition and hydrate the skin. It also leaves a silky feel when applied.
Polymethylsilsesquioxane has not been shown to clog pores. It has been deemed safe to use up to 55%, but most cosmetics use much less.
If you have concerns about using this ingredient, we recommend speaking with a professional.
Learn more about PolymethylsilsesquioxaneTitanium Dioxide (TD) is a mineral UV filter widely used in sunscreens and cosmetics.
It's one of only two UV filters officially classified as "mineral" by regulatory agencies (the other being Zinc Oxide).
A really common myth is that mineral filters work by reflecting UV light off your skin like tiny mirrors.
They don't only do that; modern research shows TD protects mostly by absorbing UV radiation, the same way chemical filters do.
When researchers measured this, reflection accounted for only about 4-5% of the protection (and less than SPF 2 on its own). The other ~95% comes from absorption: the UV photons hit the particle and their energy gets soaked up by its semiconductor band gap rather than bouncing off.
So "reflects vs. absorbs" was never really the right way to split mineral from chemical filters.
TD gives broad-spectrum protection that's strongest in the UVB and UVA-2 range and weaker in the UVA-1 range. Its UVA protection isn't quite as strong as Zinc Oxide's which is why you'll often see the two paired together.
Together, they make a solid broad-spectrum system.
TD is a great pick for sensitive, acne-prone, or redness-prone skin because it's non-irritating and chemically inert. Regulatory reviews classify it as a non-sensitizer and mild-to-non-irritant.
It's also unlikely to cause the "eye sting" some chemical filters are known for.
The main trade-off is cosmetic; TD can leave a white cast and has a thicker texture. This is why mineral sunscreens are often less cosmetically elegant than chemical or hybrid formulas (and harder to shade-match on deeper skin tones).
Formulators often use micronized or nano-sized TD to cut down on white case and improve spreadability. Smaller particles scatter less visible light so the formula looks less chalky while still filtering UV.
TD is almost always bundled with coatings like Alumina, Silica, Stearic Acid, or Dimethicone. These coatings do two important jobs:
TD can be used at up to 25% in a finished sunscreen; this is the regulatory ceiling in both the US and the EU.
In practice, the amount in any given product varies a lot depending on the target SPF and whether it's paired with other UV filters.
TD is one of the most heavily vetted sunscreen ingredients out there. It is approved as a UV filter in all major markets worldwide, including the US, EU, UK, Japan, Korea, China, Australia, and Canada.
The safety evidence is solid. There was an old worry that nano particles might absorb through skin into the body but multiple studies (including on damaged, sunburned, and UV-irradiated skin) have shown that TD stays on the surface and the layer of dead skin cells on top of everything else.
There's also no evidence of carcinogenicity, mutagenicity, or reproductive toxicity from dermal exposure of this ingredient.
For those who have seen the headline about a 2022 EU ban on TD, that was on TD as a food additive (a complete separate use from topical sunscreen).
There are ongoing questions about how nano-TD might affect marine ecosystems. As of now, there has been no conclusive evidence that any form of TD (or any other sunscreen filter) harms coral reefs or marine life.
The science is still developing and it's a space worth watching rather than packing over.
However, several destinations have reef-safety sunscreen rules that restrict certain chemical filters and steer visitors toward mineral, non-nano options. If you're traveling somewhere with these rules, a non-nano mineral sunscreen is the safe bet.
Learn more about Titanium DioxideTriethoxycaprylylsilane is a silicon-based surface modifier that makes sunscreens feel silky and makeup stay put.
Its main job is to coat mineral particles like titanium dioxide, zinc oxide, and color pigments in a thin, oily layer so they spread smoothly, don't clump, and stick to skin better.
This ingredient is typically used at low levels (up to 2.5% in eyeshadow and 1% in lipstick).
Learn more about TriethoxycaprylylsilaneWater. It's the most common cosmetic ingredient of all. You'll usually see it at the top of ingredient lists, meaning that it makes up the largest part of the product.
So why is it so popular? Water most often acts as a solvent - this means that it helps dissolve other ingredients into the formulation.
You'll also recognize water as that liquid we all need to stay alive. If you see this, drink a glass of water. Remember to stay hydrated!
Learn more about Water